在線發(fā)生離子色譜法檢測(cè)水中碘化物等9種指標(biāo)
作者:曾麗蘭1， 雷萍1， 王維康2（1.深圳市水文水質(zhì)中心，廣東 深圳 518055；2.深圳市利源水務(wù)設(shè)計(jì)咨詢有限公司，廣東 深圳 518030）
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[1]曾麗蘭,雷萍,王維康.在線發(fā)生離子色譜法檢測(cè)水中碘化物等9種指標(biāo)[J].中國(guó)給水排水,2022,38(18):134-138.
ZENG Li-lan,LEI Ping,WANG Wei-kang.Online Generation Ion Chromatography for Determination of Nine Indicators Such as Iodide in Water[J].China Water & Wastewater,2022,38(18):134-138.點(diǎn)擊復(fù)制
在線發(fā)生離子色譜法檢測(cè)水中碘化物等9種指標(biāo)
中國(guó)給水排水[ISSN:1000-4062/CN:12-1073/TU] 卷: 第38卷 期數(shù): 2022年第18期 頁(yè)碼: 134-138 欄目: 出版日期: 2022-09-17
Title:Online Generation Ion Chromatography for Determination of Nine Indicators Such as Iodide in Water
作者:曾麗蘭1， 雷萍1， 王維康2（1.深圳市水文水質(zhì)中心，廣東 深圳 518055；2.深圳市利源水務(wù)設(shè)計(jì)咨詢有限公司，廣東 深圳 518030）
Author(s):ZENG Li-lan1， LEI Ping1， WANG Wei-kang2（1. Shenzhen Hydrology and Water Quality Center， Shenzhen 518055， China； 2. Shenzhen Liyuan Water Design & Consulting Co. Ltd.， Shenzhen 518030， China）
關(guān)鍵詞:飲用水源; 飲用水; 離子色譜法; 碘化物; 草甘膦; 高氯酸鹽
Keywords:drinking water sources; drinking water; ion chromatography; iodide; glyphosate; perchlorate
摘要:針對(duì)供水行業(yè)高氯酸鹽、碘化物等指標(biāo)檢測(cè)需求，開發(fā)了可在20 min內(nèi)檢測(cè)碘化物、草甘膦、高氯酸鹽、溴化物、氟化物、氯化物、硝酸鹽氮、硫酸鹽和磷酸鹽等9種化合物的淋洗液在線發(fā)生離子色譜方法。碘化物、草甘膦、高氯酸鹽、溴化物檢出限分別達(dá)到0.002、0.005、0.001、0.004 mg/L，其余5種化合物檢出限均滿足相關(guān)標(biāo)準(zhǔn)要求。在各指標(biāo)定量限水平的平均加標(biāo)回收率達(dá)到96.3%~104%，相對(duì)標(biāo)準(zhǔn)偏差為0.68%~3.79%。該方法簡(jiǎn)單、靈敏度高，可實(shí)現(xiàn)對(duì)飲用水和水源水多指標(biāo)的高效分析。應(yīng)用該方法對(duì)南方某市水源水相關(guān)指標(biāo)進(jìn)行檢測(cè)的結(jié)果表明，碘化物和溴化物在水源水中普遍檢出，平均含量分別為0.028 mg/L和0.037 mg/L，個(gè)別水庫(kù)達(dá)到高碘水平；高氯酸鹽和草甘膦均未檢出；氟化物、氯化物、硝酸鹽氮、硫酸鹽等指標(biāo)均滿足地表水Ⅱ類標(biāo)準(zhǔn)。對(duì)50個(gè)水廠出廠水水樣進(jìn)行檢測(cè)，碘化物、高氯酸鹽、草甘膦、溴化物和磷酸鹽均未檢出，其他指標(biāo)符合生活飲用水水質(zhì)要求。建議關(guān)注水廠供水工藝的碘代和溴代消毒副產(chǎn)物風(fēng)險(xiǎn)。
Abstract:To meet the requirements of perchlorate and iodide detection in water supply industry, an online generation ion chromatography method was developed for the detection of nine compounds such as iodide, glyphosate, perchlorate, bromide, fluoride, chloride, nitrate nitrogen, sulfate and phosphate in 20 min. The detection limits of iodide, glyphosate, perchlorate, bromide were 0.002 mg/L, 0.005 mg/L, 0.001 mg/L and 0.004 mg/L, respectively, and those of other five compounds met the requirements of relevant standards. At the quantitative limit level，the average recoveries were 96.3%-104% and the relative standard deviations were 0.68%-3.79%. The method is simple and sensitive, and can be applied to analyze drinking water and source water efficiently. The method was applied to detect the relevant indexes of source water in a city in south China. Iodide and bromide were widely detected in the source water with average concentrations of 0.028 mg/L and 0.037 mg/L, respectively, and high iodine concentration was detected in particular reservoir. Perchlorate and glyphosate were not detected. Fluoride, chloride, nitrate nitrogen, sulfate and other indicators met the limitations specified in surface water class Ⅱ standard. Water samples from 50 waterworks were tested. Iodide, perchlorate, glyphosate, bromide and phosphate were not detected, and other indicators met the requirements specified in drinking water quality standard. It is suggested to pay attention to the risk of iodine and bromine disinfection byproducts in water supply process.
相似文獻(xiàn)/References:
[1]李秀虹,劉則華,林青,等.中日兩國(guó)自來水水質(zhì)的重要影響因素全面對(duì)比分析[J].中國(guó)給水排水,2018,34(20):24.
LI Xiu hong,LIU Ze hua,LIN Qing,et al.Comprehensive Comparison of Important Factors Influencing Drinking Water Quality between China and Japan[J].China Water & Wastewater,2018,34(18):24.
[2]李萌萌,梁濤,王真臻,等.日本飲用水水質(zhì)檢測(cè)標(biāo)準(zhǔn)化概述及啟示[J].中國(guó)給水排水,2022,38(3):131.
LIMeng-meng,LIANGTao,WANGZhen-zhen,et al.Overview and Enlightenment of Standardization of Drinking Water Quality Detection in Japan[J].China Water & Wastewater,2022,38(18):131.
[3]侯琮語(yǔ),李佳賓,付宛宜,等.臭氧/陶瓷膜-活性炭組合工藝處理農(nóng)村飲用水中試[J].中國(guó)給水排水,2022,38(8):38.
HOUCong-yu,LIJia-bin,FUWan-yi,et al.A Combined Ozone/Ceramic Membrane and Activated Carbon Process for Rural Drinking Water Treatment: A Pilot Study[J].China Water & Wastewater,2022,38(18):38.
[4]劉梓晶,李紅巖,王新,等.熒光光譜-KNN算法用于腐殖酸種類識(shí)別和定量[J].中國(guó)給水排水,2022,38(23):56.
LIUZi-jing,LIHong-yan,WANGXin,et al.Identification and Quantification of Humic Acid Based on K-Nearest Neighbor Algorithm Combined with Fluorescence Spectra[J].China Water & Wastewater,2022,38(18):56.
[5]陳曉晨,肖亮,陳之歆,等.給水管網(wǎng)生物穩(wěn)定性研究：現(xiàn)狀、挑戰(zhàn)與未來[J].中國(guó)給水排水,2023,39(10):1.
CHENXiao-chen,XIAOLiang,CHENZhi-xin,et al.A Review on the Biological Stability of Drinking Water Distribution System: Current Status, Challenges and Future[J].China Water & Wastewater,2023,39(18):1.
[6]肖融,方超,段友麗,等.飲用水中總有機(jī)鹵素分析方法的研究進(jìn)展[J].中國(guó)給水排水,2023,39(18):36.
XIAORong,FANGChao,DUANYou-li,et al.Research Progress of Total Organic Halogen Analysis in Drinking Water[J].China Water & Wastewater,2023,39(18):36.
更新日期/Last Update: 2022-09-17
[1]曾麗蘭,雷萍,王維康.在線發(fā)生離子色譜法檢測(cè)水中碘化物等9種指標(biāo)[J].中國(guó)給水排水,2022,38(18):134-138.
ZENG Li-lan,LEI Ping,WANG Wei-kang.Online Generation Ion Chromatography for Determination of Nine Indicators Such as Iodide in Water[J].China Water & Wastewater,2022,38(18):134-138.
點(diǎn)擊復(fù)制
ZENG Li-lan,LEI Ping,WANG Wei-kang.Online Generation Ion Chromatography for Determination of Nine Indicators Such as Iodide in Water[J].China Water & Wastewater,2022,38(18):134-138.
在線發(fā)生離子色譜法檢測(cè)水中碘化物等9種指標(biāo)
中國(guó)給水排水[ISSN:1000-4062/CN:12-1073/TU] 卷: 第38卷 期數(shù): 2022年第18期 頁(yè)碼: 134-138 欄目: 出版日期: 2022-09-17
- Title:
- Online Generation Ion Chromatography for Determination of Nine Indicators Such as Iodide in Water
- Keywords:
- drinking water sources; drinking water; ion chromatography; iodide; glyphosate; perchlorate
- 摘要:
- 針對(duì)供水行業(yè)高氯酸鹽、碘化物等指標(biāo)檢測(cè)需求，開發(fā)了可在20 min內(nèi)檢測(cè)碘化物、草甘膦、高氯酸鹽、溴化物、氟化物、氯化物、硝酸鹽氮、硫酸鹽和磷酸鹽等9種化合物的淋洗液在線發(fā)生離子色譜方法。碘化物、草甘膦、高氯酸鹽、溴化物檢出限分別達(dá)到0.002、0.005、0.001、0.004 mg/L，其余5種化合物檢出限均滿足相關(guān)標(biāo)準(zhǔn)要求。在各指標(biāo)定量限水平的平均加標(biāo)回收率達(dá)到96.3%~104%，相對(duì)標(biāo)準(zhǔn)偏差為0.68%~3.79%。該方法簡(jiǎn)單、靈敏度高，可實(shí)現(xiàn)對(duì)飲用水和水源水多指標(biāo)的高效分析。應(yīng)用該方法對(duì)南方某市水源水相關(guān)指標(biāo)進(jìn)行檢測(cè)的結(jié)果表明，碘化物和溴化物在水源水中普遍檢出，平均含量分別為0.028 mg/L和0.037 mg/L，個(gè)別水庫(kù)達(dá)到高碘水平；高氯酸鹽和草甘膦均未檢出；氟化物、氯化物、硝酸鹽氮、硫酸鹽等指標(biāo)均滿足地表水Ⅱ類標(biāo)準(zhǔn)。對(duì)50個(gè)水廠出廠水水樣進(jìn)行檢測(cè)，碘化物、高氯酸鹽、草甘膦、溴化物和磷酸鹽均未檢出，其他指標(biāo)符合生活飲用水水質(zhì)要求。建議關(guān)注水廠供水工藝的碘代和溴代消毒副產(chǎn)物風(fēng)險(xiǎn)。
- Abstract:
- To meet the requirements of perchlorate and iodide detection in water supply industry, an online generation ion chromatography method was developed for the detection of nine compounds such as iodide, glyphosate, perchlorate, bromide, fluoride, chloride, nitrate nitrogen, sulfate and phosphate in 20 min. The detection limits of iodide, glyphosate, perchlorate, bromide were 0.002 mg/L, 0.005 mg/L, 0.001 mg/L and 0.004 mg/L, respectively, and those of other five compounds met the requirements of relevant standards. At the quantitative limit level，the average recoveries were 96.3%-104% and the relative standard deviations were 0.68%-3.79%. The method is simple and sensitive, and can be applied to analyze drinking water and source water efficiently. The method was applied to detect the relevant indexes of source water in a city in south China. Iodide and bromide were widely detected in the source water with average concentrations of 0.028 mg/L and 0.037 mg/L, respectively, and high iodine concentration was detected in particular reservoir. Perchlorate and glyphosate were not detected. Fluoride, chloride, nitrate nitrogen, sulfate and other indicators met the limitations specified in surface water class Ⅱ standard. Water samples from 50 waterworks were tested. Iodide, perchlorate, glyphosate, bromide and phosphate were not detected, and other indicators met the requirements specified in drinking water quality standard. It is suggested to pay attention to the risk of iodine and bromine disinfection byproducts in water supply process.
相似文獻(xiàn)/References:
[1]李秀虹,劉則華,林青,等.中日兩國(guó)自來水水質(zhì)的重要影響因素全面對(duì)比分析[J].中國(guó)給水排水,2018,34(20):24.
LI Xiu hong,LIU Ze hua,LIN Qing,et al.Comprehensive Comparison of Important Factors Influencing Drinking Water Quality between China and Japan[J].China Water & Wastewater,2018,34(18):24.
[2]李萌萌,梁濤,王真臻,等.日本飲用水水質(zhì)檢測(cè)標(biāo)準(zhǔn)化概述及啟示[J].中國(guó)給水排水,2022,38(3):131.
LIMeng-meng,LIANGTao,WANGZhen-zhen,et al.Overview and Enlightenment of Standardization of Drinking Water Quality Detection in Japan[J].China Water & Wastewater,2022,38(18):131.
[3]侯琮語(yǔ),李佳賓,付宛宜,等.臭氧/陶瓷膜-活性炭組合工藝處理農(nóng)村飲用水中試[J].中國(guó)給水排水,2022,38(8):38.
HOUCong-yu,LIJia-bin,FUWan-yi,et al.A Combined Ozone/Ceramic Membrane and Activated Carbon Process for Rural Drinking Water Treatment: A Pilot Study[J].China Water & Wastewater,2022,38(18):38.
[4]劉梓晶,李紅巖,王新,等.熒光光譜-KNN算法用于腐殖酸種類識(shí)別和定量[J].中國(guó)給水排水,2022,38(23):56.
LIUZi-jing,LIHong-yan,WANGXin,et al.Identification and Quantification of Humic Acid Based on K-Nearest Neighbor Algorithm Combined with Fluorescence Spectra[J].China Water & Wastewater,2022,38(18):56.
[5]陳曉晨,肖亮,陳之歆,等.給水管網(wǎng)生物穩(wěn)定性研究：現(xiàn)狀、挑戰(zhàn)與未來[J].中國(guó)給水排水,2023,39(10):1.
CHENXiao-chen,XIAOLiang,CHENZhi-xin,et al.A Review on the Biological Stability of Drinking Water Distribution System: Current Status, Challenges and Future[J].China Water & Wastewater,2023,39(18):1.
[6]肖融,方超,段友麗,等.飲用水中總有機(jī)鹵素分析方法的研究進(jìn)展[J].中國(guó)給水排水,2023,39(18):36.
XIAORong,FANGChao,DUANYou-li,et al.Research Progress of Total Organic Halogen Analysis in Drinking Water[J].China Water & Wastewater,2023,39(18):36.
更新日期/Last Update: 2022-09-17
